Nitrogen Electrons



Valence Shell Electrons. The outer orbital of a nitrogen atom, the (p^2 ) orbital, can carry up to six electrons, just like all other (p ) orbitals. However, a nitrogen atom will only have three of these slots filled. When reacting with other chemicals, it will often try to take electrons from other atoms/ions to get a full octet.

A nitrogen atom has 5 electrons in its outer shell. Nitrogen is in group 5 of the periodic table. Two nitrogen atoms will each share three electrons to form three covalent bonds and make a nitrogen molecule (N 2). A nitrogen atom has the electronic structure represented by 1 s2 2 s2 2 p3. The five outer shell electrons screen the nuclear charge quite poorly, with the result that the effective nuclear charge felt at the covalent radius distance is relatively high. Each n, we can have at most two electrons (one with spin up and one with spin down). If we have N electrons, at T = 0, the electron occupies the lowest N’2 states. The energy of the highest filled state is known as the Fermi energy eF. The momentum of this state is known as the Fermi momentum PF. In the case of a negative ion, there are fewer protons than electrons. For example, N 3-has a -3 charge; therefore, it has gained 3 electrons compared to the neutral state. Nitrogen’s atomic number is 7, therefore this ion has 10 electrons.

Element Nitrogen - N

Comprehensive data on the chemical element Nitrogen is provided on this page; including scores of properties, element names in many languages, most known nuclides of Nitrogen. Common chemical compounds are also provided for many elements. In addition technical terms are linked to their definitions and the menu contains links to related articles that are a great aid in one's studies.

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Overview of Nitrogen

  • Atomic Number: 7
  • Group: 15
  • Period: 2
  • Series: Nonmetals

Nitrogen's Name in Other Languages

  • Latin: Nitrogenium
  • Czech: Dusík
  • Croatian: Dušik
  • French: Azote
  • German: Stickstoff - r
  • Italian: Azoto
  • Norwegian: Nitrogen
  • Portuguese: Nitrogênio
  • Russian: Азот
  • Spanish: Nitrógeno
  • Swedish: Kväve

Atomic Structure of Nitrogen

  • Atomic Radius: 0.75Å
  • Atomic Volume: 17.3cm3/mol
  • Covalent Radius: 0.75Å
  • Cross Section (Thermal Neutron Capture) σa/barns: 1.91
  • Crystal Structure: Hexagonal
  • Electron Configuration:
    1s2 2s2p3
  • Electrons per Energy Level: 2,5
    Shell Model
  • Ionic Radius: 0.13Å
  • Filling Orbital: 2p3
  • Number of Electrons (with no charge): 7
  • Number of Neutrons (most common/stable nuclide): 7
  • Number of Protons: 7
  • Oxidation States:±3,5,4,2
  • Valence Electrons: 2s2p3
    Electron Dot Model

Chemical Properties of Nitrogen

  • Electrochemical Equivalent: 0.10452g/amp-hr
  • Electron Work Function:
  • Electronegativity: 3.04 (Pauling); 3.07 (Allrod Rochow)
  • Heat of Fusion: 0.3604kJ/mol
  • Incompatibilities:
  • Ionization Potential
    • First: 14.534
    • Second: 29.601
    • Third: 47.448
  • Valence Electron Potential (-eV): 550

Physical Properties of Nitrogen

  • Atomic Mass Average: 14.00674
  • Boiling Point: 77.5K -195.65°C -320.17°F
  • Coefficient of lineal thermal expansion/K-1: N/A
  • Conductivity
    Electrical:
    Thermal: 0.0002598 W/cmK
  • Density: 1.2506g/L @ 273K & 1atm
  • Description:
    Colorless, odorless, tasteless gas
  • Enthalpy of Atomization: 472.8 kJ/mole @ 25°C
  • Enthalpy of Fusion: 0.36 kJ/mole
  • Enthalpy of Vaporization: 2.79 kJ/mole
  • Flammablity Class:
  • Freezing Point:see melting point
  • Heat of Vaporization: 2.7928kJ/mol
  • Melting Point: 63.29K -209.86°C -345.75°F
  • Molar Volume: 17.3 cm3/mole
  • Optical Refractive Index: 1.000298 (gas) 1.197 (liquid)
  • Physical State (at 20°C & 1atm): Gas
  • Specific Heat: 1.04J/gK

Regulatory / Health

  • CAS Number
    • 7727-37-9
  • OSHAPermissible Exposure Limit (PEL)
    • No limits set by OSHA
  • OSHA PEL Vacated 1989
    • No limits set by OSHA
  • NIOSHRecommended Exposure Limit (REL)
    • No limits set by NIOSH
  • Levels In Humans:
    Note: this data represents naturally occuring levels of elements in the typical human, it DOES NOT represent recommended daily allowances.
    • Blood/mg dm-3: 34300
    • Bone/p.p.m: 43000
    • Liver/p.p.m: 72000
    • Muscle/p.p.m: 72000
    • Daily Dietary Intake: n/a
    • Total Mass In Avg. 70kg human: 1.8 kg
  • Discovery Year: 1772
  • Name Origin:
    Greek: zôê (vie).
  • Abundance of Nitrogen:
    • Earth's Crust/p.p.m.: 25
    • Seawater/p.p.m.:
      • Atlantic Suface: 0.00008
      • Atlantic Deep: 0.27
      • Pacific Surface: 0.00008
      • Pacific Deep: 0.54
    • Atmosphere/p.p.m.: 780900
    • Sun (Relative to H=1E12): 8.71E+07
  • Sources of Nitrogen:
    Nitrogen can be made by liquification and then fractional distillation of the air. It is very easily done commercially. It can also be made by heating NaN3 to 300 degrees C. Annual world wide production is around 44,000,000 tons.
  • Uses of Nitrogen:
    Nitrogen has many industrial uses in the gaseous forms, but probably the most interesting is liquid nitrogen, which is extremely cold. Items that must be frozen to extremely low temperatures for preservation are frequently stored in liquid nitrogen. Fertility clinics store sperm, eggs and embryos used to help infertile couples become pregnant in ampoules in liquid nitrogen.Since nitrogen gas is very stable, at standard temperature and pressure, it is used as the air in inert welding atmospheres. Documents, foods and chemicals are sometimes stored in nitrogen to keep them from oxidizing or reacting with air or water.
  • Additional Notes:

    Nitrogen in the elemental form was considered to be inert and was even named ozote which refers to the fact that it is not reactive. Of course nitrogen does form compounds, but the gaseous form consists of diamers (2 nitrogens bonded together). The diamer is very stable.

    Nitrogen is a major element in organic compounds, especially proteins. Some nitrogen compounds are highly reactive. Trinitrotoluene is TNT or dynamite. Ammonium Nitrate is a fertilizer, but was used as the major explosive ingredient in the Oklahoma City bombing. Anfo, or Ammonium Nitrate and fuel oil mixture is the primary explosive used in the mining industry because it is inexpensive, easy to manufacture and can be easily manufactured near the mine site thus reducing the risks and expenses related to the transportation of explosives. Nitrates, Nitrites and Azides (all nitrogen compounds are either oxidizers or reactives and will react violently under the right conditions.

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References

A list of reference sources used to compile the data provided on our periodic table of elements can be found on the main periodic table page.

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  • Molar Mass Calculations and Javascript Calculator
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  • Chemical Database
    This database focuses on the most common chemical compounds used in the home and industry.

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